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(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-?N)trichloridocobalt(II).

ABSTRACT: The title compound, [Co(C(10)H(21)N(2))Cl(3)], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups. These mol-ecules inter-act by way of C-H?Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array.

SUBMITTER: Luachan S 

PROVIDER: S-EPMC2968682 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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(1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-κN)trichloridocobalt(II).

Luachan Sanchai S   Yotnoi Bunlawee B   Prior Timothy J TJ   Rujiwatra Apinpus A  

Acta crystallographica. Section E, Structure reports online 20090225 Pt 3

The title compound, [Co(C(10)H(21)N(2))Cl(3)], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and st  ...[more]