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Bis{2-[6-(1H-benzimidazol-2-yl-?N)-2-pyridyl-?N]benzimidazolato-?N}manganese(II).

ABSTRACT: In the title compound, [Mn(C(19)H(12)N(5))(2)], each Mn(II) atom lies on a position of site symmetry 222 and has a distorted octa-hedral coordination geometry made up from six N atoms of two tridentate 2-[6-(1H-benzimidazol-2-yl)-2-pyrid-yl]benz-imidazolate ligands. The complex mol-ecules are linked into layers parallel to (001) by N-H?N hydrogen bonds, with the H atoms disordered over four symmetry-equivalent non-coordinated N atoms.

SUBMITTER: Bai XQ

PROVIDER: S-EPMC2969020 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Bis{2-[6-(1H-benzimidazol-2-yl-κN)-2-pyridyl-κN]benzimidazolato-κN}manganese(II).

Bai Xian-Qun XQ Zhang Shu-Hua SH

Acta crystallographica. Section E, Structure reports online 20090314 Pt 4

In the title compound, [Mn(C(19)H(12)N(5))(2)], each Mn(II) atom lies on a position of site symmetry 222 and has a distorted octa-hedral coordination geometry made up from six N atoms of two tridentate 2-[6-(1H-benzimidazol-2-yl)-2-pyrid-yl]benz-imidazolate ligands. The complex mol-ecules are linked into layers parallel to (001) by N-H⋯N hydrogen bonds, with the H atoms disordered over four symmetry-equivalent non-coordinated N atoms. ...[more]

PMID: 21582344

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