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Bis[2-(1H-benzimidazol-2-yl)-phenolato]-dimethanol-manganese(III) chloride.

ABSTRACT: In the title compound, [Mn(C(13)H(9)N(2)O)(2)(CH(3)OH)(2)]Cl, the Mn(III) atom (site symmetry ) is coordinated by two N,O-bidentate 2-(1H-benzimidazol-2-yl)phenolate ligands and two methanol mol-ecules, to generate a distorted trans-MnN(2)O(4) octa-hedral geometry for the metal ion. The dihedral angle between the aromatic ring systems in the ligand is 16.0?(3)°. In the crystal structure, the complex cations and chloride anions are linked by O-H?Cl and N-H?Cl hydrogen bonds. The chloride ion lies on a crystallographic twofold axis.

SUBMITTER: Ma Q 

PROVIDER: S-EPMC2979052 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Bis[2-(1H-benzimidazol-2-yl)-phenolato]-dimethanol-manganese(III) chloride.

Ma Qi Q   Zhu Miaoli M   Feng Sisi S   Lu Liping L  

Acta crystallographica. Section E, Structure reports online 20100414 Pt 5

In the title compound, [Mn(C(13)H(9)N(2)O)(2)(CH(3)OH)(2)]Cl, the Mn(III) atom (site symmetry ) is coordinated by two N,O-bidentate 2-(1H-benzimidazol-2-yl)phenolate ligands and two methanol mol-ecules, to generate a distorted trans-MnN(2)O(4) octa-hedral geometry for the metal ion. The dihedral angle between the aromatic ring systems in the ligand is 16.0 (3)°. In the crystal structure, the complex cations and chloride anions are linked by O-H⋯Cl and N-H⋯Cl hydrogen bonds. The chloride ion lies  ...[more]

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