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3-Mesityl-2-oxo-1-oxaspiro-[4.4]non-3-en-4-yl 4-chloro-benzoate.

ABSTRACT: The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo-pentane ring displays an envelope conformation with the atom at the flap position 0.611?(2)?Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3?(2) and 81.9?(2)°, respectively, with the 2,4,6-trimethyl-phenyl and 4-chloro-phenyl rings. The dihedral angle between the two benzene rings is 76.6?(1)°. In the crystal, mol-ecules are linked through weak inter-molecular C-H?O hydrogen bonds, forming chains running along the c axis.

SUBMITTER: Ji MH 

PROVIDER: S-EPMC2969026 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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3-Mesityl-2-oxo-1-oxaspiro-[4.4]non-3-en-4-yl 4-chloro-benzoate.

Ji Ming-Hua MH   Xia Min M   Zhu Guo-Nian GN   Zhao Jin-Hao JH  

Acta crystallographica. Section E, Structure reports online 20090306 Pt 4

The title compound, C(24)H(23)ClO(4), is a potent insecticide and miticide. The five-membered cyclo-pentane ring displays an envelope conformation with the atom at the flap position 0.611 (2) Å out of the mean plane formed by the other four atoms. The furan ring makes dihedral angles of 71.3 (2) and 81.9 (2)°, respectively, with the 2,4,6-trimethyl-phenyl and 4-chloro-phenyl rings. The dihedral angle between the two benzene rings is 76.6 (1)°. In the crystal, mol-ecules are linked through weak i  ...[more]

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