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Diaqua-[N,N'-bis-(3-carboxy-prop-2-enoyl)pyridine-2,6-dicarbo-hydrazidato(2-)]cadmium(II) N,N-dimethyl-formamide disolvate.

ABSTRACT: In the title complex, [Cd(C(15)H(11)N(5)O(8))(H(2)O)(2)]·2C(3)H(7)NO, the Cd(II) ion is located on a twofold rotation axis and is seven-coordinated in a distorted penta-gonal-bipyramidal manner. The asymmetric unit comprises one metal ion, one doubly deprotonated N,N'-bis-(3-carboxy-prop-2-eno-yl)pyridine-2,6-dicarbohydrazide ligand, two coordinating water mol-ecules and two dimethyl-formamide solvent mol-ecules. In the crystal, a two-dimensional network is formed through N-H?O and O-H?O hydrogen bonds.

SUBMITTER: Cao Q

PROVIDER: S-EPMC2969067 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Diaqua-[N,N'-bis-(3-carboxy-prop-2-enoyl)pyridine-2,6-dicarbo-hydrazidato(2-)]cadmium(II) N,N-dimethyl-formamide disolvate.

Cao Quanfu Q Li Dacheng D

Acta crystallographica. Section E, Structure reports online 20090331 Pt 4

In the title complex, [Cd(C(15)H(11)N(5)O(8))(H(2)O)(2)]·2C(3)H(7)NO, the Cd(II) ion is located on a twofold rotation axis and is seven-coordinated in a distorted penta-gonal-bipyramidal manner. The asymmetric unit comprises one metal ion, one doubly deprotonated N,N'-bis-(3-carboxy-prop-2-eno-yl)pyridine-2,6-dicarbohydrazide ligand, two coordinating water mol-ecules and two dimethyl-formamide solvent mol-ecules. In the crystal, a two-dimensional network is formed through N-H⋯O and O-H⋯O hydroge ...[more]

PMID: 21582396

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