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(Methyldiphenyl-phospho-ranylidene)-ammonium chloride.

ABSTRACT: The title compound, C(13)H(15)NP(+)·Cl(-), was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyl-imino-phosphine. The dihedral angle between the phenyl rings in the cation is 61.5?(3)°. In the crystal structure, inter-molecular N-H?Cl hydrogen bonds links the two components, forming a centrosymmetric 2 + 2 aggregate.

SUBMITTER: Valerio-Cardenas C

PROVIDER: S-EPMC2969268 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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(Methyldiphenyl-phospho-ranylidene)-ammonium chloride.

Valerio-Cárdenas Cintya C Ortiz-Frade Luis L Grévy M Jean-Michel JM

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

The title compound, C(13)H(15)NP(+)·Cl(-), was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyl-imino-phosphine. The dihedral angle between the phenyl rings in the cation is 61.5 (3)°. In the crystal structure, inter-molecular N-H⋯Cl hydrogen bonds links the two components, forming a centrosymmetric 2 + 2 aggregate. ...[more]

PMID: 21582794

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