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Diaqua-bis(2-methyl-1H-imidazol-3-ium-4,5-dicarboxyl-ato-?O,O')magnesium.


ABSTRACT: The title compound, [Mg(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)], was prepared by reaction of Mg(NO(3))(2) and 2-methyl-1H-imidazole-4,5-dicarboxylic acid under hydro-thermal conditions. The Mg(II) atom lies on an inversion centre and displays a distorted octa-hedral coordination geometry. An extended three-dimensional network of inter-molecular O-H?O and N-H?O hydrogen bonds stabilizes the crystal structure.

SUBMITTER: Li YL 

PROVIDER: S-EPMC2969309 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Diaqua-bis(2-methyl-1H-imidazol-3-ium-4,5-dicarboxyl-ato-κO,O')magnesium.

Li Yi Liang YL   Guo Xin X   Wang Ju Xian JX   Wang Yu Cheng YC  

Acta crystallographica. Section E, Structure reports online 20090613 Pt 7


The title compound, [Mg(C(6)H(5)N(2)O(4))(2)(H(2)O)(2)], was prepared by reaction of Mg(NO(3))(2) and 2-methyl-1H-imidazole-4,5-dicarboxylic acid under hydro-thermal conditions. The Mg(II) atom lies on an inversion centre and displays a distorted octa-hedral coordination geometry. An extended three-dimensional network of inter-molecular O-H⋯O and N-H⋯O hydrogen bonds stabilizes the crystal structure. ...[more]

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