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Diaqua-bis-[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II).

ABSTRACT: In the title complex, [Co(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Co(II) atom has a distorted octa-hedral coordination, formed by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two O atoms from two water mol-ecules. Intra-molecular N-H?O and O-H?O hydrogen bonds are present. In the crystal, inter-molecular O-H?O hydrogen bonds link the complex mol-ecules into a chain along [010].

SUBMITTER: Zhang Z

PROVIDER: S-EPMC3011445 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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Diaqua-bis-[2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinato]cobalt(II).

Zhang Zhong Z Liu Ji-Zhong JZ Gao Peng P Huang Zhong-Jing ZJ

Acta crystallographica. Section E, Structure reports online 20101113 Pt 12

In the title complex, [Co(C(13)H(14)N(3)O(3))(2)(H(2)O)(2)], the Co(II) atom has a distorted octa-hedral coordination, formed by four N atoms from two (±)-2-(5-isopropyl-5-methyl-4-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinate ligands and two O atoms from two water mol-ecules. Intra-molecular N-H⋯O and O-H⋯O hydrogen bonds are present. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the complex mol-ecules into a chain along [010]. ...[more]

PMID: 21589239

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