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Bis(2-propyl-1H-imidazol-3-ium) bis-(pyridine-2,6-dicarboxyl-ato-?O,N,O)cadmate(II).

ABSTRACT: The title salt, (C(6)H(11)N(2))(2)[Cd(C(7)H(3)NO(4))(2)], displays a discrete mononuclear structure, in which the central Cd(II) atom is six-coordinated in a distorted octa-hedral coordination geometry by two N and four O atoms from two different pyridine-2,6-dicarboxyl-ate anions in an O(2),N,O(6)-tridentate chelation mode. The crystal packing is stabilized by N-H?O hydrogen bonds and ?-? inter-actions [centroid-centroid distance = 3.576?(5)?Å].

SUBMITTER: Dong GY

PROVIDER: S-EPMC3151894 | biostudies-other | 2011 Jul

REPOSITORIES: biostudies-other

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Bis(2-propyl-1H-imidazol-3-ium) bis-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cadmate(II).

Dong Gui-Ying GY Liu Tong-Fei TF He Cui-Hong CH Deng Xiao-Chen XC Shi Xiao-Ge XG

Acta crystallographica. Section E, Structure reports online 20110630 Pt 7

The title salt, (C(6)H(11)N(2))(2)[Cd(C(7)H(3)NO(4))(2)], displays a discrete mononuclear structure, in which the central Cd(II) atom is six-coordinated in a distorted octa-hedral coordination geometry by two N and four O atoms from two different pyridine-2,6-dicarboxyl-ate anions in an O(2),N,O(6)-tridentate chelation mode. The crystal packing is stabilized by N-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.576 (5) Å]. ...[more]

PMID: 21836832

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