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2,2'-Dimethyl-2,2'-(m-phenyl-ene-dimethyl-ene)propane-dinitrile.

ABSTRACT: The title compound, C(16)H(14)N(4), features an aromatic ring with two 2,2'-dicyano-propyl residues in positions 1 and 3, which are located above and below the ring plane. The two residues differ in their conformation with respect to the aromatic ring: whereas one of the C(meth-yl)-C-C(methyl-ene)-C(aromatic) torsion angles is gauche [68.93?(12)°], the other one is fully staggered [177.63?(9)°]. The crystal structure is stabilized by C-H?N hydrogen-bonding inter-actions.

SUBMITTER: Zhao J 

PROVIDER: S-EPMC2969357 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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2,2'-Dimethyl-2,2'-(m-phenyl-ene-dimethyl-ene)propane-dinitrile.

Zhao Junmei J   Böhmer Volker V   Bolte Michael M  

Acta crystallographica. Section E, Structure reports online 20090620 Pt 7

The title compound, C(16)H(14)N(4), features an aromatic ring with two 2,2'-dicyano-propyl residues in positions 1 and 3, which are located above and below the ring plane. The two residues differ in their conformation with respect to the aromatic ring: whereas one of the C(meth-yl)-C-C(methyl-ene)-C(aromatic) torsion angles is gauche [68.93 (12)°], the other one is fully staggered [177.63 (9)°]. The crystal structure is stabilized by C-H⋯N hydrogen-bonding inter-actions. ...[more]

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