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Bis(thio-semicarbazide)nickel(II) bis-[2-(thio-semicarbazonometh-yl)benzene-sulfonate] dihydrate.

ABSTRACT: In the title compound, [Ni(CH(5)N(3)S)(2)](C(8)H(8)N(3)O(3)S(2))(2)·2H(2)O, the Ni(II) atom lies on a inversion centre and is four-coordinated by two N and two S atoms of two thio-semicarbazide ligands in an almost square-planar coordination. In the crystal structure, the molecules are linked into a three-dimensional network via C-H?O, C-H?N, N-H?O, N-H?S and O-H?O hydrogen bonds.

SUBMITTER: Zhang W 

PROVIDER: S-EPMC2969405 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Bis(thio-semicarbazide)nickel(II) bis-[2-(thio-semicarbazonometh-yl)benzene-sulfonate] dihydrate.

Zhang Wei W   Chen Yuan-Tao YT  

Acta crystallographica. Section E, Structure reports online 20090613 Pt 7

In the title compound, [Ni(CH(5)N(3)S)(2)](C(8)H(8)N(3)O(3)S(2))(2)·2H(2)O, the Ni(II) atom lies on a inversion centre and is four-coordinated by two N and two S atoms of two thio-semicarbazide ligands in an almost square-planar coordination. In the crystal structure, the molecules are linked into a three-dimensional network via C-H⋯O, C-H⋯N, N-H⋯O, N-H⋯S and O-H⋯O hydrogen bonds. ...[more]

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