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Trans-Bis(dimethyl sulfoxide-?O)bis-(thio-semicarbazide-?N,S)cadmium dipicrate dihydrate.

ABSTRACT: In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa-coordinated in an octahedral fashion by two thio-semicarbazide mol-ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol-ecules. The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate. In the crystal, these units are linked by a number of O-H?O and N-H?S hydrogen bonds and weak C-H?O inter-actions, forming a three-dimensional network.

SUBMITTER: Shanthakumari R 

PROVIDER: S-EPMC3050361 | biostudies-literature | 2010 Dec

REPOSITORIES: biostudies-literature

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trans-Bis(dimethyl sulfoxide-κO)bis-(thio-semicarbazide-κN,S)cadmium dipicrate dihydrate.

Shanthakumari R R   Hema R R   Ramamurthy K K   Stoeckli-Evans Helen H  

Acta crystallographica. Section E, Structure reports online 20101224 Pt 1

In the cation of the title compound, [Cd(CH(5)N(3)S)(2)(C(2)H(6)OS)(2)](C(6)H(2)N(3)O(7))(2)·2H(2)O, the Cd(II) atom is located on an inversion center. It is hexa-coordinated in an octahedral fashion by two thio-semicarbazide mol-ecules, which coordinate in a bidentate manner via the S and N atoms, and to the O atom of two dimethyl sufoxide (DMSO) mol-ecules. The charges are equilibrated by two picrate anions and the complex crystallizes as a dihydrate. In the crystal, these units are linked by  ...[more]

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