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{6,6'-Dimethoxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O}iron(II) monohydrate.

ABSTRACT: In the title complex, [Fe(C(22)H(24)N(2)O(4))]·H(2)O, the Fe(II) center is four-coordinated by two O and two N atoms from 2,2'-[6,6'-dimethoxy-cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphen-olate (L) ligands in a distorted square-planar geometry. Uncoordinated water and FeL mol-ecules are paired via inter-molecular water-meth-oxy O-H?O hydrogen bonds.

SUBMITTER: Yan PF

PROVIDER: S-EPMC2969507 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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{6,6'-Dimethoxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O}iron(II) monohydrate.

Yan Peng-Fei PF Bao Yan Y Li Hong-Feng HF Li Guang-Ming GM

Acta crystallographica. Section E, Structure reports online 20090627 Pt 7

In the title complex, [Fe(C(22)H(24)N(2)O(4))]·H(2)O, the Fe(II) center is four-coordinated by two O and two N atoms from 2,2'-[6,6'-dimethoxy-cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphen-olate (L) ligands in a distorted square-planar geometry. Uncoordinated water and FeL mol-ecules are paired via inter-molecular water-meth-oxy O-H⋯O hydrogen bonds. ...[more]

PMID: 21582750

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{2,2'-[6,6'-Dimethoxy-cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O}cobalt(II) monohydrate.

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Project description:In the title dinuclear salen-type complex, [CuEu(C(22)H(24)N(2)O(4))(NO(3))(3)(CH(3)OH)], the Cu(II) ion is five-coordinated to two imine N atoms and two phenolate O atoms and one O from the bridging nitrate group. The Eu(III) ion is ligated to three nitrate groups, four O atoms from the salen-type ligand and one methanol mol-ecule, leading to a distorted tenfold coordination for the rare earth cation. One of the three nitrate anions is disordered over two positions in a 0.66 (5):0.34 (5) ratio.

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{?-6,6'-Dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)lutetium(III).

Project description:In the title dinuclear Cu(II)-Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6'-dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu-O = 2.230?(3)-2.621?(4)?Å]. The slightly distorted square-planar four-coordinate Cu(II) atom comprises two imine N atoms [Cu-N = 1.903?(4) and 1.912?(4)?Å] and two phenolate O atoms from the ligand mol-ecule [Cu-O = 1.897?(3) and 1.906?(3)?Å]. All atoms of the cyclo-hexane ring of the ligand mol-ecule are disordered over two sets of sites with equal occupancy.

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Project description:In the title mol-ecule, C(20)H(22)N(2)O(2)Se(4), the dihedral angle between the pendant aromatic rings is 67.1 (2)°. The conformation is stabilized by two intra-molecular O-H⋯N hydrogen bonds.

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