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Bis[4-(dimethyl-amino)pyridinium] penta-bromidochloridostannate(IV).

ABSTRACT: In the title compound, (C(7)H(11)N(2))(2)[SnBr(5)Cl], there is Br/Cl disorder in 0.6561?(12):0.3439?(12) and 0.8438?(12):0.1561?(12) ratios over two of three halide sites in the centrosymmetric anion, such that an overall formulation of [SnBr(5)Cl](2-) arises. In the crystal, associations of two cations and one anion linked by N-H?Br hydrogen bonds occur.

SUBMITTER: Jang Y

PROVIDER: S-EPMC2969538 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Bis[4-(dimethyl-amino)pyridinium] penta-bromidochloridostannate(IV).

Jang Yong Y Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

In the title compound, (C(7)H(11)N(2))(2)[SnBr(5)Cl], there is Br/Cl disorder in 0.6561 (12):0.3439 (12) and 0.8438 (12):0.1561 (12) ratios over two of three halide sites in the centrosymmetric anion, such that an overall formulation of [SnBr(5)Cl](2-) arises. In the crystal, associations of two cations and one anion linked by N-H⋯Br hydrogen bonds occur. ...[more]

PMID: 21583011

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