Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[4-(dimethyl-amino)pyridinium] hexa-kis[bromido/chlorido(0.78/0.22)]stannate(IV).

ABSTRACT: The Sn atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(4.67)Cl(1.33)], lies on a center of symmetry within an octa-hedron of disordered halogen atoms. The three independent halogen atoms are each a mixture of bromine and chlorine atoms [with site occupancies for bromine of 0.614?(1), 0.831?(1) and 0.888?(1)]. An N-H? hydrogen bond is present.

SUBMITTER: Lo KM

PROVIDER: S-EPMC2969252 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis[4-(dimethyl-amino)pyridinium] hexa-kis[bromido/chlorido(0.78/0.22)]stannate(IV).

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

The Sn atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(4.67)Cl(1.33)], lies on a center of symmetry within an octa-hedron of disordered halogen atoms. The three independent halogen atoms are each a mixture of bromine and chlorine atoms [with site occupancies for bromine of 0.614 (1), 0.831 (1) and 0.888 (1)]. An N-H⋯ hydrogen bond is present. ...[more]

PMID: 21582659

Similar Datasets

Bis(2-bromo-pyridinium) hexa-bromido-stannate(IV).

Project description:The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnBr(6)], contains one cation and one half-anion. The [SnBr(6)](2-) anion is located on an inversion center and forms a quasi-regular octa-hedral arrangement. The crystal structure consists of two-dimensional supra-molecular layers assembled via hydrogen-bonding inter-actions of N-H?Br-Sn [D?A = 3.375?(13)-3.562?(13)?Å and D-H?A = 127-142°, along with C-Br?Br synthons [3.667?(2) and 3.778?(3)?Å]. These layers are parallel to the bc plane and built up from anions inter-acting extensively with the six surrounding cations.

| S-EPMC2961614 | biostudies-literature

Bis(2-bromo-pyridinium) hexa-chlorido-stannate(IV).

Project description:The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2-) anion is located on an inversion center and forms a quasi-regular octa-hedral arrangement. Hydrogen-bonding inter-actions of two kinds, viz. N-H⋯Cl-Sn and C-H⋯Cl-Sn, along with Cl⋯Br inter-actions [3.4393 (15) Å], connect the ions in the crystal structure into two-dimensional supra-molecular arrays. These supra-molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter-acting with six symmetry-related surrounding cations.

| S-EPMC2961104 | biostudies-literature

Bis(2,6-dimethyl-pyridinium) hexa-chlorido-platinate(IV).

Project description:The asymmetric unit of the title compound, (C(7)H(10)N)(2)[PtCl(6)], contains one independent protonated 2,6-dimethyl-pyridinium cation and half of a centrosymmetric [PtCl(6)](2-) anion. The Pt atom has an octa-hedral coordination. In the crystal structure, inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds result in the formation of a supra-molecular structure. There is a π-π contact between the pyridine rings [centroid-centroid distance = 4.235 (1) Å].

| S-EPMC2960473 | biostudies-literature

4-Amidino-pyridinium hexa-chlorido-stannate(IV) dihydrate.

Project description:In the title hydrated mol-ecular salt {systematic name: 4-[amino-(iminium-yl)meth-yl]pyridin-1-ium hexa-chlorido-stannate(IV) dihydrate}, (C6H9N3)[SnCl6]·2H2O, the tin atom lies on a crystallographic inversion centre and the organic cation shows whole-mol-ecule disorder. Numerous N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds link the components in the crystal.

| S-EPMC9462015 | biostudies-literature

Bis(diisopropyl-ammonium) hexa-chlorido-stannate(IV).

Project description:The title compound, (C(6)H(16)N)(2)[SnCl(6)], crystallizes with one diisopropyl-ammonium cation lying on a general position and the hexa-chloridostannate(IV) anion about a centre of inversion. The [SnCl(6)](2-) anion undergoes a slight distortion from octa-hedral symmetry as the result of the formation of four unforked charge-supported N-H?Cl hydrogen bonds. The hydrogen bonds between the cations and anions form layers perpendicular to [101]. These layers are built by 24-membered rings which can be classified with an R(8) (8)(24) graph-set descriptor. According to this hydrogen-bonding motif, the title compound is isostructural with (C(6)H(16)N)(2)[IrCl(6)].

| S-EPMC3515144 | biostudies-literature

Tetra-kis(4-chloro-anilinium) hexa-chlorido-stannate(IV) dichloride.

Project description:The asymmetric unit of the title compound, (C(6)H(7)ClN)(4)[SnCl(6)]Cl(2), comprises two 4-chloro-anilinium cations, half of an [SnCl(6)](2-) anion and a Cl(-) anion. The Sn(IV) atom, located on a special position on a twofold rotation axis, exhibits an octa-hedral environment. In the crystal, mol-ecules are linked by N-H?Cl hydrogen bonds between the 4-chloro-anilinium cations, [SnCl(6)](2-) anions and Cl(-) anions.

| S-EPMC3379112 | biostudies-literature

Bis(trimethyl-phenyl-ammonium) hexa-[bromido/chlorido(0.792/0.208)]stannate(IV).

Project description:In the title mol-ecular salt, [C(6)H(5)(CH(3))(3)N](2)[SnBr(4.75)Cl(1.25)], the Sn(IV) atom (site symmetry ) adopts an octa-hedral coordination geometry. The Br and Cl atoms are disordered over three sites in 0.7415?(13):0.2585?(14), 0.8514?(14):0.1486?(14) and 0.7821?(14):0.2179?(14) ratios.

| S-EPMC2983897 | biostudies-other

Bis(4-acetyl-anilinium) hexa-chlorido-stannate(IV).

Project description:In the title compound, (C(8)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom exists in an octa-hedral coordination environment. In the crystal, inter-molecular N-H?O and N-H?Cl hydrogen bonds link the cations and anions into a three-dimensional framework.

| S-EPMC3089185 | biostudies-literature

Synthesis, crystal structure and Hirshfeld surface of bis-(2-amino-pyridinium) hexa-chlorido-stannate(IV).

Project description:In the title mol-ecular salt, (C5H7N2)2[SnCl6], the cation is protonated at the pyridine N atom and the complete dianion is generated by a crystallographic centre of symmetry. In the crystal, N-H⋯Cl hydrogen bonds link the components into a three-dimensional network built up from the stacking of alternate cationic and anionic layers. The nature of the inter-molecular inter-actions has been analysed in terms of the Hirshfeld surfaces of the cations and the anions. The thermal behaviour and the Raman spectrum of the title compound are reported.

| S-EPMC7405591 | biostudies-literature

Bis(2-meth-oxy-anilinium) hexa-bromido-stannate(IV) dihydrate.

Project description:The asymmetric unit of the title compound, (C7H10NO)2[SnBr6]·2H2O, contains one cation, one half-dianion and one lattice water mol-ecule. The [SnBr6](2-) dianion, located on an inversion center, exhibits a highly distorted octa-hedral coordination environment, with Sn-Br bond lengths ranging from 2.2426 (9) to 3.0886 (13) Å. In the crystal, O-H⋯Br, N-H⋯Br, N-H⋯O and C-H⋯Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and lattice water mol-ecules) and cationic layers parallel to ab plane.

| S-EPMC3885007 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data