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1-Benzyl-3-(2-methoxy-phen-yl)imidazolium tetra-fluoro-borate.

ABSTRACT: In the title compound, C(17)H(17)N(2)O(+)·BF(4) (-), the central imidazolium ring makes dihedral angles of 74.58?(9) and 40.10?(6)° with the phenyl and 2-methoxy-phenyl rings, respectively. In the crystal, a strong ?-? inter-action is observed between the imidazolium and 2-methoxy-phenyl rings, with a centroid-centroid distance of 3.5115?(15)?Å. In addition, C-H?F and C-H?O hydrogen bonds and C-H?? inter-actions involving the -phenyl ring are observed.

SUBMITTER: Jiang P

PROVIDER: S-EPMC2970015 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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1-Benzyl-3-(2-methoxy-phen-yl)imidazolium tetra-fluoro-borate.

Jiang Ping P

Acta crystallographica. Section E, Structure reports online 20090819 Pt 9

In the title compound, C(17)H(17)N(2)O(+)·BF(4) (-), the central imidazolium ring makes dihedral angles of 74.58 (9) and 40.10 (6)° with the phenyl and 2-methoxy-phenyl rings, respectively. In the crystal, a strong π-π inter-action is observed between the imidazolium and 2-methoxy-phenyl rings, with a centroid-centroid distance of 3.5115 (15) Å. In addition, C-H⋯F and C-H⋯O hydrogen bonds and C-H⋯π inter-actions involving the -phenyl ring are observed. ...[more]

PMID: 21577584

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