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Benzyl-ammonium tetra-fluoro-borate 18-crown-6 clathrate.

ABSTRACT: The reaction of benzyl-ammonium tetra-fluoro-borate and 18-crown-6 in a methano-lic solution yields the title compound, C(7)H(10)N(+)·BF(4) (-)·C(12)H(24)O(6)O6, which displays a supra-molecular structure. The -NH(3) (+) substituent of the benzyl-ammonium cation forms a 1:1 supra-molecular rotator-stator structure by N-H?O hydrogen-bonding inter-actions.

SUBMITTER: Zhao MM

PROVIDER: S-EPMC3007038 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature

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Benzyl-ammonium tetra-fluoro-borate 18-crown-6 clathrate.

Zhao Min Min MM

Acta crystallographica. Section E, Structure reports online 20100609 Pt 7

The reaction of benzyl-ammonium tetra-fluoro-borate and 18-crown-6 in a methano-lic solution yields the title compound, C(7)H(10)N(+)·BF(4) (-)·C(12)H(24)O(6)O6, which displays a supra-molecular structure. The -NH(3) (+) substituent of the benzyl-ammonium cation forms a 1:1 supra-molecular rotator-stator structure by N-H⋯O hydrogen-bonding inter-actions. ...[more]

PMID: 21587849

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