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Catena-Poly[[[bis-(1,10-phenanthroline-?N,N')manganese(II)]-?-2,2'-dithio-dibenzoato-?O,O] methanol hemisolvate monohydrate].

ABSTRACT: The title complex, {[Mn(C(14)H(8)O(4)S(2))(C(12)H(8)N(2))(2)]·0.5CH(3)OH·H(2)O}(n), has a one-dimensional chain structure in which the Mn(II) atom is six-coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and two O atoms from two 2,2'-dithio-dibenzoate (L) ligands. The L ligands adopt a bis-(monodentate) (syn-anti) coordination mode and bridge adjacent Mn(II) centres, generating a chain running along [201]. Adjacent chains are linked into a two-dimensional network, parallel to (10), via inter-chain C-H?? and ?-? stacking [centroid-centroid distance = 3.477?(1)?Å] inter-actions. The structure also contains numerous hydrogen-bonding interactions, which further link the two-dimensional entities into a three-dimensional supramolecular network.

SUBMITTER: Zhou LM 

PROVIDER: S-EPMC2970205 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[[bis-(1,10-phenanthroline-κN,N')manganese(II)]-μ-2,2'-dithio-dibenzoato-κO,O] methanol hemisolvate monohydrate].

Zhou Li-Ming LM   Zhang Qiang Q   Hu Min M  

Acta crystallographica. Section E, Structure reports online 20090916 Pt 10

The title complex, {[Mn(C(14)H(8)O(4)S(2))(C(12)H(8)N(2))(2)]·0.5CH(3)OH·H(2)O}(n), has a one-dimensional chain structure in which the Mn(II) atom is six-coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and two O atoms from two 2,2'-dithio-dibenzoate (L) ligands. The L ligands adopt a bis-(monodentate) (syn-anti) coordination mode and bridge adjacent Mn(II) centres, generating a chain running along [201]. Adjacent chains are linked into a two-dimensional network, parallel  ...[more]

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