Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichlorido(4,5-diaza-fluoren-9-one-?N,N')palladium(II).

ABSTRACT: The structure of the title compound, [PdCl(2)(C(11)H(6)N(2)O)], shows a nearly square-planar geometry for the Pd(II) atom within a Cl(2)N(2) donor set.

SUBMITTER: Xu ZG

PROVIDER: S-EPMC2970311 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichlorido(4,5-diaza-fluoren-9-one-κN,N')palladium(II).

Xu Zhi-Guang ZG Liu Hai-Yang HY Zhan Qing-Guang QG Chen Jian J Xu Min-Jian MJ

Acta crystallographica. Section E, Structure reports online 20090905 Pt 10

The structure of the title compound, [PdCl(2)(C(11)H(6)N(2)O)], shows a nearly square-planar geometry for the Pd(II) atom within a Cl(2)N(2) donor set. ...[more]

PMID: 21577704

Similar Datasets

Tetra-aqua-(4,5-diaza-fluoren-9-one-?N,N')nickel(II) dinitrate.

Project description:The title compound, [Ni(C(11)H(6)N(2)O)(H(2)O)(4)](NO(3))(2), was prepared by the reaction of Ni(NO(3))(2) and 4,5-diaza-fluoren-9-one (dafo). The crystal packing consists of a three-dimensional network via O-H?O hydrogen bonds between the coordin-ated water mol-ecules and the nitrate anions. The Ni atom lies on a special position (Wyckoff position 4e, site symmetry 2), as does the carbonyl O atom.

| S-EPMC2970992 | biostudies-literature

Triaqua-(benzene-1,3-dicarboxyl-ato)(4,5-diaza-fluoren-9-one)cadmium(II) penta-hydrate.

Project description:In the title compound, [Cd(C(8)H(4)O(4))(C(11)H(6)N(2)O)(H(2)O)(3)]·5H(2)O, the Cd(II) atom is seven-coordinated by two N atoms from one bidentate phenanthroline-derived ligand and by five O atoms, two from one bidentate benzene-1,3-dicarboxyl-ate (1,3-BDC) ligand and three from water mol-ecules, in a distorted penta-gonal-bipyramidal geometry. Neighbouring units inter-act through ?-? inter-actions [centroid-centroid distances = 3.380?(3) and 3.283?(4)?Å]. Finally, three types of O-H?O hydrogen bonds exist between coordinated dissociative water mol-ecules and hybridization water mol-ecules and carboxyl-ate O atoms, resulting in a two-dimensional network parallel to (010).

| S-EPMC3011731 | biostudies-literature

9-Oxo-4,5-diaza-fluoren-4-ium tetra-chloridoaurate(III)-4,5-diaza-fluoren-9-one (1/1).

Project description:The Au(III) atom in the title compound, (C(11)H(7)N(2)O)[AuCl(4)]·C(11)H(6)N(2)O, is in a nearly square-planar environment defined by four Cl atoms. The protonated 9-oxo-4,5-diaza-fluoren-4-ium cation forms an N-H?N hydrogen bond with the neutral 4,5-diaza-fluoren-9-one mol-ecule.

| S-EPMC2968535 | biostudies-other

(4,5-Diaza-fluoren-9-one-?N,N')bis-(thio-cyanato-?S)mercury(II).

Project description:In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate diaza-fluoren-9-one ligand and two thio-cyanate anions. In the crystal, inter-molecular C-H?N and C-H?O hydrogen bonds are effective in the stabilization of the structure.

| S-EPMC3099883 | biostudies-other

Hexaaqua-zinc(II) bis-(2,4,5-tricarboxybenzoate) 4,5-diaza-fluoren-9-one disolvate dihydrate.

Project description:The asymmetric unit of the title complex, [Zn(H(2)O)(6)](C(10)H(5)O(8))(2)·2C(11)H(6)N(2)O·2H(2)O, contains one half of the complex cation with the Zn(II) ion located on an inversion center, a monovalent 2,4,5-tricarboxybenzoate (1,2,4,5-BTC) counter-anion, a 4,5-diaza-fluoren-9-one (DAFO) mol-ecule and an uncoordinated water mol-ecule. In the crystal structure, O-H?O and O-H?N hydrogen bonds link the cations, anions and water mol-ecules into a three-dimensional network.

| S-EPMC3006871 | biostudies-other

Diaqua-bis(9-oxo-4,5-diaza-fluoren-3-olato-κN,O)cadmium(II).

Project description:The title compound, [Cd(C(11)H(5)N(2)O(2))(2)(H(2)O)(2)], is a mononuclear complex consisting of a Cd(II) atom, two 3-hydr-oxy-4,5-diaza-fluoren-9-one ligands and two coordinated water mol-ecules. The Cd(II) atom, lying on a twofold axis, displays a distorted octa-hedral coordintion. Adjacent mol-ecules are linked by O-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distance = 3.84 (1) Å], leading to a one-dimensional chain. Weak C-H⋯O hydrogen bonds connect the chains into a two-dimensional supra-molecular structure.

| S-EPMC2960196 | biostudies-literature

N-(4,5-Diaza-fluoren-9-yl-idene)aniline.

Project description:In the mol-ecule of the title compound, C(17)H(11)N(3), the 4,5-diaza-fluorenyl-idene unit is nearly planar and is oriented with respect to the phenyl ring at a dihedral angle of 75.75?(3)°. In the crystal structure, the mol-ecules are aligned in the [100] direction in such a way that neighbouring 4,5-diaza-fluorenyl-idene planes face each other in an anti-parallel fashion.

| S-EPMC2961656 | biostudies-literature

9-Phenyl-4,5-diaza-9H-fluoren-9-ol monohydrate.

Project description:The title compound, C(17)H(12)N(2)O·H(2)O, was synthesized by the reaction of 4,5-diaza-fluoren-9-one with a Grignard reagent in ether (the reaction mixture being hydrolysed with saturated NH(4)Cl solution), and crystallizes with two organic mol-ecules and two water mol-ecules in the asymmetric unit. The 4,5-diaza-fluorene fragment is approximately planar, with r.m.s. deviations of 0.0448 and 0.0198 Å in the two mol-ecules. The dihedral angles between the 4,5-diaza-fluorene planes and the phenyl ring are 80.49 (6) and 76.57 (7)°. The crystal packing features O-H⋯N and O-H⋯O hydrogen bonds involving the bridging solvent water mol-ecules, which link the mol-ecules into a three-dimensional network.

| S-EPMC3379391 | biostudies-literature

Dichlorido(4,7-diaza-1-azoniacyclo-nonane-?N,N)palladium(II) p-toluene-sulfonate.

Project description:The title compound, [PdCl(2)(C(6)H(16)N(3))](C(7)H(7)SO(3)), consists of a Pd(II) atom bonded to two N atoms of the 1,4,7-triaza-cyclo-nonane (TACN) ligand and two chloride ions, which define a distorted square-planar geometry. The third N atom of the TACN ligand is protonated and hydrogen bonds to the p-toluene-sulfonate anion. The Cl-Pd-Cl angle is larger than the N-Pd-N angle. The packing is dominated by layers, which are formed by the criss-crossing of two different hydrogen-bonded chains. One chain is composed of hydrogen-bonded Pd(TACNH)Cl(2) (+) cations, while the second is formed through hydrogen bonding between the p-toluene-sulfonate anion and the Pd(TACNH)Cl(2) (+) cation.

| S-EPMC2979570 | biostudies-literature

4,5-Diaza-9H-fluoren-9-imine.

Project description:In the title compound, C(11)H(7)N(3), the diaza-fluorene rings are almost coplanar with an r.m.s. deviation of 0.0160?Å. In the crystal structure, C-H?N hydrogen bonds link mol-ecules into sheets parallel to the ab plane. Mol-ecules are also stacked regularly along the c axis by a variety of ?-? inter-actions with centroid-centroid distances in the range 3.527?(2)-3.908?(2)?Å.

| S-EPMC3006907 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data