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(4,5-Diaza-fluoren-9-one-?N,N')bis-(thio-cyanato-?S)mercury(II).

ABSTRACT: In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate diaza-fluoren-9-one ligand and two thio-cyanate anions. In the crystal, inter-molecular C-H?N and C-H?O hydrogen bonds are effective in the stabilization of the structure.

SUBMITTER: Notash B

PROVIDER: S-EPMC3099883 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

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(4,5-Diaza-fluoren-9-one-κN,N')bis-(thio-cyanato-κS)mercury(II).

Notash Behrouz B Safari Nasser N Amani Vahid V

Acta crystallographica. Section E, Structure reports online 20110309 Pt 4

In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate diaza-fluoren-9-one ligand and two thio-cyanate anions. In the crystal, inter-molecular C-H⋯N and C-H⋯O hydrogen bonds are effective in the stabilization of the structure. ...[more]

PMID: 21753948

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