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Bis[?-2-(aminosulfanyl)pyridine(1-)]bis-[(?-penta-methyl-cyclo-penta-dien-yl)iridium(III)] diiodide.

ABSTRACT: In the title dinuclear iridium(III) complex, [Ir(2)(C(10)H(15))(2)(C(5)H(5)N(2)S)(2)]I(2), the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1-) [(2-py)SNH] ligands in a ?-(2-py)SNH-?(2)N(py),N(NH):?N(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center, resulting in a planar Ir(2)N(2) ring with an Ir-N(py) bond length of 2.085?(9)?Å and bridging Ir-N(NH) bonds of 2.110?(9) and 2.113?(9)?Å. The two (2-py)S units have mutually anti configurations with respect to the Ir(2)N(2) ring.

SUBMITTER: Sekioka Y

PROVIDER: S-EPMC2970401 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Bis[μ-2-(aminosulfanyl)pyridine(1-)]bis-[(η-penta-methyl-cyclo-penta-dien-yl)iridium(III)] diiodide.

Sekioka Yusuke Y Suzuki Takayoshi T

Acta crystallographica. Section E, Structure reports online 20090919 Pt 10

In the title dinuclear iridium(III) complex, [Ir(2)(C(10)H(15))(2)(C(5)H(5)N(2)S)(2)]I(2), the iridium(III) atoms are bridged by 2-(aminosulfanyl)pyridine(1-) [(2-py)SNH] ligands in a μ-(2-py)SNH-κ(2)N(py),N(NH):κN(NH) mode. The dinuclear complex cation lies on a crystallographic inversion center, resulting in a planar Ir(2)N(2) ring with an Ir-N(py) bond length of 2.085 (9) Å and bridging Ir-N(NH) bonds of 2.110 (9) and 2.113 (9) Å. The two (2-py)S units have mutually anti configurations with r ...[more]

PMID: 21577749

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