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Tri-?-chlorido-bis-[(?(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III)] hexa-fluorido-phosphate from synchrotron radiation.

ABSTRACT: In the title complex salt, [{(?(5)-C5Me5)Rh}2(?-Cl)3]PF6, the dinuclear, single-charged cation is formed by the cojoining of two classic (?(5)-C5Me5)RhCl3 'piano-stool' units by bridging of the three choride ligand 'legs'. The crystal structure shows several close H?F contacts between the hexa-fluorido-phosphate counter-ions and the C5Me5 ligands.

SUBMITTER: Ezzedinloo L

PROVIDER: S-EPMC4029212 | biostudies-literature | 2014 Jan

REPOSITORIES: biostudies-literature

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Tri-μ-chlorido-bis-[(η(5)-penta-methyl-cyclo-penta-dien-yl)rhodium(III)] hexa-fluorido-phosphate from synchrotron radiation.

Ezzedinloo Lida L Shrestha Sumi S Bhadbhade Mohan M Colbran Stephen S

Acta crystallographica. Section E, Structure reports online 20131211 Pt 1

In the title complex salt, [{(η(5)-C5Me5)Rh}2(μ-Cl)3]PF6, the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C5Me5)RhCl3 'piano-stool' units by bridging of the three choride ligand 'legs'. The crystal structure shows several close H⋯F contacts between the hexa-fluorido-phosphate counter-ions and the C5Me5 ligands. ...[more]

PMID: 24855466

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