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1,6-Bis(diphenyl-arsino)hexa-ne.

ABSTRACT: The title diphenyl-arsino compound, C(30)H(32)As(2) or Ph(2)As(CH(2))(6)AsPh(2), lies about a crystallographic inversion centre located at the mid-point of the central Csp(3)-Csp(3) bond of the methyl-ene chain. The two benzene rings bonded to As are inclined to one another at a dihedral angle of 75.98?(8)°. In the crystal structure, weak inter-molecular C-H?? inter-actions stack the mol-ecules down the b axis.

SUBMITTER: Shawkataly OB

PROVIDER: S-EPMC2970425 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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1,6-Bis(diphenyl-arsino)hexa-ne.

Shawkataly Omar Bin OB Khan Imthyaz Ahmed IA Goh Jia Hao JH Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20090930 Pt 10

The title diphenyl-arsino compound, C(30)H(32)As(2) or Ph(2)As(CH(2))(6)AsPh(2), lies about a crystallographic inversion centre located at the mid-point of the central Csp(3)-Csp(3) bond of the methyl-ene chain. The two benzene rings bonded to As are inclined to one another at a dihedral angle of 75.98 (8)°. In the crystal structure, weak inter-molecular C-H⋯π inter-actions stack the mol-ecules down the b axis. ...[more]

PMID: 21578027

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