1,1'-Dimethyl-4,4'-[(2,4-diphenyl-cyclo-butane-1,3-di-yl)dipyridinium-(E)-1-methyl-4-styrylpyridinium-benzene-sulfonate (0.15/1.70/2).

ABSTRACT: In the title compound, 1.70C(14)H(14)N(+)·0.15C(28)H(28)N(2) (2+)·2C(6)H(5)O(3)S(-), the monocation exists in the E configuration with respect to the ethenyl C=C double bond and is close to planar, the dihedral angle between the pyridinium and phenyl ring being 5.20?(13)°. The dication lies about an inversion centre. In the crystal, the dication occupies almost the same site occupied by monocations at (x, y, z) and (2?-?x, 1?-?y, 1?-?z). The O atoms of the anion are disordered over two positions with occupancies of 0.75 and 0.25. In the crystal, the cations are stacked in an anti-parallel manner along the a axis, whereas the anions are linked into chains along the same direction by C-H?O hydrogen bonds. In addition, C-H?? and ?-? inter-actions [centroid-centroid distance = 3.593?(9) or 3.6705?(16)?Å] are observed.

SUBMITTER: Fun HK 

PROVIDER: S-EPMC2970487 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature