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Bis(2,2'-bi-1H-imidazole-?N,N)(thio-cyanato-?N)copper(II) chloride.

ABSTRACT: In the title salt, [Cu(NCS)(C(6)H(6)N(4))(2)]Cl, the Cu(II) atom adopts a five-coordinated square-pyramidal geometry consisting of an N atom from a thio-cyanate anion and four N atoms from two chealting biimidazole ligands. The thio-cyanate ligand occupies the axial position and is, like the Cu(II) centre, located on a mirror plane. The cation and anion are linked into a linear chain by N-H?S and N-H?Cl hydrogen bonds.

SUBMITTER: Ma Q 

PROVIDER: S-EPMC2971028 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis(2,2'-bi-1H-imidazole-κN,N)(thio-cyanato-κN)copper(II) chloride.

Ma Qi Q   Meng Shuang-Ming SM   Feng Feng F   Lu Li-Ping LP   Zhu Miao-Li ML  

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the title salt, [Cu(NCS)(C(6)H(6)N(4))(2)]Cl, the Cu(II) atom adopts a five-coordinated square-pyramidal geometry consisting of an N atom from a thio-cyanate anion and four N atoms from two chealting biimidazole ligands. The thio-cyanate ligand occupies the axial position and is, like the Cu(II) centre, located on a mirror plane. The cation and anion are linked into a linear chain by N-H⋯S and N-H⋯Cl hydrogen bonds. ...[more]

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