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Tetra-kis(1-allyl-1H-imidazole-?N)bis-(thio-cyanato-?N)manganese(II).

ABSTRACT: The structure of the title compound, [Mn(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol-ecules of [Mn(NCS)(2)(Aim)(4)] (Aim = 1-allyl-imidazole), which contain a compressed octa-hedral MnN(6) chromophore (site symmetry [Formula: see text]). The NCS(-) anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn-N(Aim) and Mn-N(NCS) distances are 2.270 and 2.229?Å, respectively. Weak C-H?N inter-actions contribute to the crystal packing stability.

SUBMITTER: Zhao J

PROVIDER: S-EPMC3254281 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Tetra-kis(1-allyl-1H-imidazole-κN)bis-(thio-cyanato-κN)manganese(II).

Zhao Juan J Jin Yan-Ling YL

Acta crystallographica. Section E, Structure reports online 20111203 Pt 1

The structure of the title compound, [Mn(NCS)(2)(C(6)H(8)N(2))(4)], consists of isolated mol-ecules of [Mn(NCS)(2)(Aim)(4)] (Aim = 1-allyl-imidazole), which contain a compressed octa-hedral MnN(6) chromophore (site symmetry [Formula: see text]). The NCS(-) anions are trans and four N atoms from the Aim ligands define the equatorial plane. The mean Mn-N(Aim) and Mn-N(NCS) distances are 2.270 and 2.229 Å, respectively. Weak C-H⋯N inter-actions contribute to the crystal packing stability. ...[more]

PMID: 22259383

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