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(2,2'-Bipyridine-?N,N')diiodido-palladium(II).


ABSTRACT: The asymmetric unit of the title complex, [PdI(2)(C(10)H(8)N(2))], contains one half of the formula unit. The Pd(2+) ion is located on a twofold rotation axis and is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2'-bipyridine ligand and two iodide ions. The compound displays inter-molecular ?-? inter-actions between the pyridine rings of the ligand, the shortest centroid-centroid distance being 4.220?(4)?Å.

SUBMITTER: Ha K 

PROVIDER: S-EPMC2971767 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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(2,2'-Bipyridine-κN,N')diiodido-palladium(II).

Ha Kwang K  

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12


The asymmetric unit of the title complex, [PdI(2)(C(10)H(8)N(2))], contains one half of the formula unit. The Pd(2+) ion is located on a twofold rotation axis and is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 2,2'-bipyridine ligand and two iodide ions. The compound displays inter-molecular π-π inter-actions between the pyridine rings of the ligand, the shortest centroid-centroid distance being 4.220 (4) Å. ...[more]

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