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Dibromido(1,10-phenanthroline-?N,N')palladium(II).

ABSTRACT: In the title complex, [PdBr(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous inter-molecular ?-? inter-actions between adjacent six-membered rings, the shortest centroid-centroid distance being 3.680?(4)?Å. The nearly planar [maximum deviation 0.143?(2)?Å] mol-ecules stack in columns parallel to (101) with a Pd?Pd distance of 4.8466?(9)?Å.

SUBMITTER: Ha K

PROVIDER: S-EPMC2980023 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Dibromido(1,10-phenanthroline-κN,N')palladium(II).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20091204 Pt 1

In the title complex, [PdBr(2)(C(12)H(8)N(2))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment by two N atoms of the chelating 1,10-phenanthroline ligand and two bromide ions. The complex displays numerous inter-molecular π-π inter-actions between adjacent six-membered rings, the shortest centroid-centroid distance being 3.680 (4) Å. The nearly planar [maximum deviation 0.143 (2) Å] mol-ecules stack in columns parallel to (101) with a Pd⋯Pd distance of 4.846 ...[more]

PMID: 21579964

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