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N-(4-Chloro-phen-yl)-3-methyl-benzamide.

ABSTRACT: In the structure of the title compound, C(14)H(12)ClNO, the conformations of the N-H and C=O bonds are anti to each other. Furthermore, the conformation of the C=O bond is syn to the meta-methyl group in the benzoyl ring. The central -NH-C(=O)- amido group makes a dihedral angle of 32.4?(1)° with the benzoyl ring and 36.1?(1)° with the anilino ring. The dihedral angle between the two benzene rings is 68.4?(1)°. In the crystal, inter-molecular N-H?O hydrogen bonds link the mol-ecules into chains running along the a axis.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2971070 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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N-(4-Chloro-phen-yl)-3-methyl-benzamide.

Gowda B Thimme BT Tokarčík Miroslav M Kožíšek Jozef J Rodrigues Vinola Zeena VZ Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

In the structure of the title compound, C(14)H(12)ClNO, the conformations of the N-H and C=O bonds are anti to each other. Furthermore, the conformation of the C=O bond is syn to the meta-methyl group in the benzoyl ring. The central -NH-C(=O)- amido group makes a dihedral angle of 32.4 (1)° with the benzoyl ring and 36.1 (1)° with the anilino ring. The dihedral angle between the two benzene rings is 68.4 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains ...[more]

PMID: 21578371

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