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2-Chloro-N-(3-methyl-phen-yl)benzamide.

ABSTRACT: In the structure of the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N-H bond. The amide group forms dihedral angles of 60.1 (1) and 22.0 (1)°, respectively, with the benzoyl and aniline rings, while the angle between these rings is 38.7 (1)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis.

SUBMITTER: Rodrigues VZ

PROVIDER: S-EPMC3295494 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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2-Chloro-N-(3-methyl-phen-yl)benzamide.

Rodrigues Vinola Z VZ Gowda B Thimme BT Vrábel Viktor V Kožíšek Jozef J

Acta crystallographica. Section E, Structure reports online 20120217 Pt 3

In the structure of the title compound, C(14)H(12)ClNO, the ortho-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N-H bond. The amide group forms dihedral angles of 60.1 (1) and 22.0 (1)°, respectively, with the benzoyl and aniline rings, while the angle between these rings is 38.7 (1)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which give rise to infinite chains running along the c axis. ...[more]

PMID: 22412605

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