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Aqua{5,5'-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II).

ABSTRACT: The title mononuclear nickel(II) complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the axial position. In the crystal, the mol-ecules are linked via inter-molecular O-H?O hydrogen bonds, forming chains along the a axis.

SUBMITTER: Tang C

PROVIDER: S-EPMC2971105 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Aqua{5,5'-dimethoxy-2,2-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II).

Tang Chunbao C

Acta crystallographica. Section E, Structure reports online 20091003 Pt 11

The title mononuclear nickel(II) complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], possesses crystallographic mirror symmetry. The Ni atom is five-coordinated in a square-pyramidal geometry, with two imine N and two phenolate O atoms of the Schiff base ligand in the square plane, and the water O atom in the axial position. In the crystal, the mol-ecules are linked via inter-molecular O-H⋯O hydrogen bonds, forming chains along the a axis. ...[more]

PMID: 21578049

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