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{6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II) dimethyl-formamide monosolvate.

ABSTRACT: In the title compound, [Ni(C(18)H(18)N(2)O(4))]·C(3)H(7)NO, the central Ni(II) atom is in a square-planar O(2)N(2) coordination environment. The planar Ni-salen moieties (r.m.s. deviation for the plane through the conjugated part of the Ni-salen group = 0.07?Å) form parallel stacks in the a-axis direction, with alternating Ni?Ni separations of 3.5339?(7) and 3.6165?(7)?Å. In the crystal, there are weak inter-molecular C-H?O inter-actions involving the dimethyl-formamide O and phenolate O atoms.

SUBMITTER: Ayikoe K

PROVIDER: S-EPMC3051997 | biostudies-literature | 2011

REPOSITORIES: biostudies-literature

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{6,6'-Dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}nickel(II) dimethyl-formamide monosolvate.

Ayikoé Kouassi K Butcher Ray J RJ Gultneh Yilma Y

Acta crystallographica. Section E, Structure reports online 20110212 Pt 3

In the title compound, [Ni(C(18)H(18)N(2)O(4))]·C(3)H(7)NO, the central Ni(II) atom is in a square-planar O(2)N(2) coordination environment. The planar Ni-salen moieties (r.m.s. deviation for the plane through the conjugated part of the Ni-salen group = 0.07 Å) form parallel stacks in the a-axis direction, with alternating Ni⋯Ni separations of 3.5339 (7) and 3.6165 (7) Å. In the crystal, there are weak inter-molecular C-H⋯O inter-actions involving the dimethyl-formamide O and phenolate O atoms. ...[more]

PMID: 21522259

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