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{3,3',5,5'-Tetra-meth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}nickel(II).

ABSTRACT: The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni-N and Ni-O bond lengths of 1.8448?(14)/1.8478?(14) and 1.8536?(12)/1.8520?(12)?Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11?(5)°]. All the atoms of the meth-oxy substitutents are in the plane of the ring to which they are attached except for one which deviates slightly [0.365?(3)?Å]. In the crystal, weak C-H?O inter-molecular inter-actions connect the mol-ecules.

SUBMITTER: Assey GE

PROVIDER: S-EPMC2979626 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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{3,3',5,5'-Tetra-meth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}nickel(II).

Assey Gervas E GE Butcher Ray J RJ Gultneh Yilma Y

Acta crystallographica. Section E, Structure reports online 20100508 Pt 6

The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni-N and Ni-O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)°]. All the atoms of the meth-oxy substitutents are in the plane of the ring to which they are attached except for one which deviates slightly [0.365 (3) Å]. In the crystal, weak C-H⋯O inter-molecular inter-actions connect the mol-ecules. ...[more]

PMID: 21579278

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