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1-Phenyl-piperazine-1,4-diium tetra-chlorido-cobalt(II).

ABSTRACT: In the title mol-ecular salt, (C10H16N2)[CoCl4], the piperazine ring of the phenyl-piperazine dication adopts a chair conformation and the phenyl ring occupies an equatorial orientation. In the tetra-chlorido-cobaltate(II) dianion, the Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N-H?Cl hydrogen bonds, generating [001] chains.

SUBMITTER: Dhieb AC

PROVIDER: S-EPMC3998532 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature

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1-Phenyl-piperazine-1,4-diium tetra-chlorido-cobalt(II).

Dhieb Abdelhamid Chiheb AC Janzen Daron E DE Rzaigui Mohamed M Smirani Sta Wajda W

Acta crystallographica. Section E, Structure reports online 20140322 Pt 4

In the title mol-ecular salt, (C10H16N2)[CoCl4], the piperazine ring of the phenyl-piperazine dication adopts a chair conformation and the phenyl ring occupies an equatorial orientation. In the tetra-chlorido-cobaltate(II) dianion, the Co-Cl bond lengths for the chloride ions not accepting hydrogen bonds are significantly shorter than those for the chloride ions accepting such bonds. In the crystal, the components are linked by N-H⋯Cl hydrogen bonds, generating [001] chains. ...[more]

PMID: 24826100

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