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Bis[?-1-(2-pyridylmeth-yl)-1H-benzo-triazole]disilver(I) bis-(perchlorate).

ABSTRACT: In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth-yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer with an intra-molecular Ag?Ag separation of 4.479?(2)?Å. Inter-molecular C-H?O hydrogen-bonding inter-actions, involving uncoordinated ClO(4) (-) ions, link the binuclear units, forming a two-dimensional network parallel to (10).

SUBMITTER: Liu CS

PROVIDER: S-EPMC2971172 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis[μ-1-(2-pyridylmeth-yl)-1H-benzo-triazole]disilver(I) bis-(perchlorate).

Liu Chun-Sen CS Xiao Xian-Guo XG Hu Min M

Acta crystallographica. Section E, Structure reports online 20091028 Pt 11

In the title centrosymmetric binuclear Ag(I )complex, [Ag(2)(C(12)H(10)N(4))(2)](ClO(4))(2), each Ag(I) center is two-coordinated by one pyridine and one benzotriazole N-donor atom of two inversion-related 1-(2-pyridylmeth-yl)-1H-benzotriazole (L) ligands. This forms a unique box-like cyclic dimer with an intra-molecular Ag⋯Ag separation of 4.479 (2) Å. Inter-molecular C-H⋯O hydrogen-bonding inter-actions, involving uncoordinated ClO(4) (-) ions, link the binuclear units, forming a two-dimension ...[more]

PMID: 21578182

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