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Bis[?-N-(pyridin-2-ylmeth-yl)pyridin-3-amine-?(2) N:N']disilver(I) bis-(perchlorate) dimethyl sulfoxide disolvate.

ABSTRACT: In the binuclear title compound, [Ag2(C11H11N3)2](ClO4)2·2C2H6SO, the complex cation is centrosymmetric, with the unique Ag(I) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridine-2-ylmeth-yl)pyridine-3-amine ligands in a geometry slightly distorted from linear [N-Ag-N = 170.78?(9)°], resulting in the formation of a 16-membered cyclic dimer. The two pyridine rings coordinating to the Ag(I) atom are almost perpendicular to each other [dihedral angle = 87.73?(10)°]. Inter-molecular Ag?O inter-actions [3.149?(3) and 2.686?(3)?Å], N-H?O and C-H?O hydrogen bonds and C-H?? inter-actions between the cyclic dimers and the anions or the solvent mol-ecules lead to the formation of a three-dimensional supra-molecular network.

SUBMITTER: Moon SH

PROVIDER: S-EPMC3884244 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Bis[μ-N-(pyridin-2-ylmeth-yl)pyridin-3-amine-κ(2) N:N']disilver(I) bis-(perchlorate) dimethyl sulfoxide disolvate.

Moon Suk-Hee SH Park Ki-Min KM

Acta crystallographica. Section E, Structure reports online 20131002 Pt 11

In the binuclear title compound, [Ag2(C11H11N3)2](ClO4)2·2C2H6SO, the complex cation is centrosymmetric, with the unique Ag(I) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridine-2-ylmeth-yl)pyridine-3-amine ligands in a geometry slightly distorted from linear [N-Ag-N = 170.78 (9)°], resulting in the formation of a 16-membered cyclic dimer. The two pyridine rings coordinating to the Ag(I) atom are almost perpendicular to each other [dihedral angle = 87.73 (10)°]. Int ...[more]

PMID: 24454020

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