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N-{Bis[meth-yl(phen-yl)amino]phosphor-yl}-2,2,2-trichloro-acetamide.

ABSTRACT: In the asymmetric unit of the crystal structure of the title compound, C(16)H(17)Cl(3)N(3)O(2)P, there are two crystallograph-ically independent mol-ecules, which form dimers via N-H?O hydrogen bonding between the N-H group and the P=O group. In the mol-ecular structure, the phosphoryl group is anti to the carbonyl group. The two benzene rings are oriented at dihedral angles of 54.3?(2) and 49.7?(2)° in the two independent mol-ecules.

SUBMITTER: Znovjyak KO

PROVIDER: S-EPMC2971180 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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N-{Bis[meth-yl(phen-yl)amino]phosphor-yl}-2,2,2-trichloro-acetamide.

Znovjyak Kateryna O KO Ovchynnikov Vladimir A VA Sliva Tetyana Yu TY Shishkina Svitlana V SV Amirkhanov Vladimir M VM

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

In the asymmetric unit of the crystal structure of the title compound, C(16)H(17)Cl(3)N(3)O(2)P, there are two crystallograph-ically independent mol-ecules, which form dimers via N-H⋯O hydrogen bonding between the N-H group and the P=O group. In the mol-ecular structure, the phosphoryl group is anti to the carbonyl group. The two benzene rings are oriented at dihedral angles of 54.3 (2) and 49.7 (2)° in the two independent mol-ecules. ...[more]

PMID: 21578403

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