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(E)-2-[(4-Ethoxy-phen-yl)imino-meth-yl]-4-methoxy-phenol.


ABSTRACT: In the mol-ecule of the title compound, C(16)H(17)NO(3), the aromatic rings are oriented at a dihedral angle of 29.25?(8)°. An intra-molecular O-H?N hydrogen bond results in the formation of a nearly planar [maximum deviation 0.034?(13)?Å] six-membered ring, which is oriented at dihedral angles of 0.91?(1) and 28.91?(12)° with respect to the aromatic rings. The title mol-ecule is a phenol-imine tautomer, as evidenced by C-O, C-N and C-C bond lengths. In the crystal, mol-ecules are linked by inter-molecular C-H?O hydrogen bonds that generate C(8) chains.

SUBMITTER: Ozek A 

PROVIDER: S-EPMC2971308 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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(E)-2-[(4-Ethoxy-phen-yl)imino-meth-yl]-4-methoxy-phenol.

Ozek Arzu A   Albayrak Ciğdem C   Büyükgüngör Orhan O  

Acta crystallographica. Section E, Structure reports online 20091010 Pt 11


In the mol-ecule of the title compound, C(16)H(17)NO(3), the aromatic rings are oriented at a dihedral angle of 29.25 (8)°. An intra-molecular O-H⋯N hydrogen bond results in the formation of a nearly planar [maximum deviation 0.034 (13) Å] six-membered ring, which is oriented at dihedral angles of 0.91 (1) and 28.91 (12)° with respect to the aromatic rings. The title mol-ecule is a phenol-imine tautomer, as evidenced by C-O, C-N and C-C bond lengths. In the crystal, mol-ecules are linked by inte  ...[more]

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