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(E)-2-[(2-Amino-4,5-dibromo-phen-yl)imino-meth-yl]-6-methoxy-phenol.

ABSTRACT: The title compound, C(14)H(12)Br(2)N(2)O(2), was prepared from the condensation of 4,5-dibromo-1,2-phenyl-enediamine and 2-hydr-oxy-3-methoxy-benzaldehyde in methanol. The N=C double bond shows a trans conformation and the dihedral angle between the aromatic ring planes is 5.9?(4)°. In the crystal structure, there are intra-molecular O-H?N and N-H?N and inter-molecular N-H?O hydrogen bonds, the latter resulting in inversion dimers.

SUBMITTER: Li ZX

PROVIDER: S-EPMC2968274 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

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(E)-2-[(2-Amino-4,5-dibromo-phen-yl)imino-meth-yl]-6-methoxy-phenol.

Li Zhan-Xian ZX Yang Hui H Yu Ming M Shi Qiu-Zhi QZ Yu Ming-Ming MM

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

The title compound, C(14)H(12)Br(2)N(2)O(2), was prepared from the condensation of 4,5-dibromo-1,2-phenyl-enediamine and 2-hydr-oxy-3-methoxy-benzaldehyde in methanol. The N=C double bond shows a trans conformation and the dihedral angle between the aromatic ring planes is 5.9 (4)°. In the crystal structure, there are intra-molecular O-H⋯N and N-H⋯N and inter-molecular N-H⋯O hydrogen bonds, the latter resulting in inversion dimers. ...[more]

PMID: 21581858

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