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Ammonium tris-(3-amino-pyrazine-2-carboxyl-ato-?N,O)nickelate(II) trihydrate.

ABSTRACT: The Ni(II) atom in the title hydrated salt, (NH(4))[Ni(C(5)H(4)N(3)O(2))(3)]·3H(2)O, is N,O-chelated by the three 3-aminopyrazine-2-carboxyl-ate ligands, resulting in a distorted octa-hedral mer-NiN(3)O(3) geometry for the metal. In the crystal, the complex anion, ammonium cation and uncoordinated water mol-ecules are linked by extensive N-H?N, N-H?O, O-H?N and O-H?O hydrogen bonds, forming a three-dimensional network.

SUBMITTER: Cheng XL

PROVIDER: S-EPMC2971780 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Ammonium tris-(3-amino-pyrazine-2-carboxyl-ato-κN,O)nickelate(II) trihydrate.

Cheng Xiao-Li XL Gao Shan S Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

The Ni(II) atom in the title hydrated salt, (NH(4))[Ni(C(5)H(4)N(3)O(2))(3)]·3H(2)O, is N,O-chelated by the three 3-aminopyrazine-2-carboxyl-ate ligands, resulting in a distorted octa-hedral mer-NiN(3)O(3) geometry for the metal. In the crystal, the complex anion, ammonium cation and uncoordinated water mol-ecules are linked by extensive N-H⋯N, N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds, forming a three-dimensional network. ...[more]

PMID: 21578649

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