Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

T-3-Pentyl-r-2,c-6-diphenyl-piperidin-4-one.

ABSTRACT: In the title mol-ecule, C(22)H(27)NO, the piperidine ring adopts a chair conformation, with all substituents equatorial. The dihedral angle between the two phenyl rings is 56.90?(5)°. In the crystal, mol-ecules are linked by weak C-H?O hydrogen bonds. A C-H?? inter-action involving the phenyl ring at the 6-position is also found in the crystal structure.

SUBMITTER: Gayathri P

PROVIDER: S-EPMC2971784 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

t-3-Pentyl-r-2,c-6-diphenyl-piperidin-4-one.

Gayathri P P Jayabharathi J J Rajarajan G G Thiruvalluvar A A Butcher R J RJ

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12

In the title mol-ecule, C(22)H(27)NO, the piperidine ring adopts a chair conformation, with all substituents equatorial. The dihedral angle between the two phenyl rings is 56.90 (5)°. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds. A C-H⋯π inter-action involving the phenyl ring at the 6-position is also found in the crystal structure. ...[more]

PMID: 21578813

Similar Datasets

1,3-Dimethyl-2,6-diphenyl-piperidin-4-one.

Project description:In the title moleclue, C(19)H(21)NO, the 4-piperidone ring adopts a chair conformation in which the two benzene rings and the methyl group attached to C atoms all have equatorial orientations. In the crystal structure, centrosymmetric dimers are formed through weak inter-molecular C-H?O hydrogen bonds [the dihedral angle between the aromatic rings is 58.51?(5)°].

| S-EPMC2968156 | biostudies-other

1-Dichloro-acetyl-3,3-dimethyl-2,6-diphenyl-piperidin-4-one.

Project description:In the title compound, C(21)H(21)Cl(2)NO(2), the piperidine ring adopts a distorted boat conformation. The two phenyl rings are approximately perpendicular to each other, with a dihedral angle of 86.12 (7)°. Mol-ecules are linked into centrosymmetric dimers by pairs of bifurcated C-H⋯O hydrogen bonds, forming R(2) (2)(10) and R(2) (2)(14) ring motifs, and an intramolecular C-H⋯O link also occurs.

| S-EPMC2967931 | biostudies-literature

3,3,5,5-Tetra-methyl-r-2,c-6-diphenyl-piperidin-4-one.

Project description:The piperidone ring of the title compound, C(21)H(25)NO, adopts a chair conformation with the two phenyl groups equatorially oriented and cis to each other. In the crystal, mol-ecules are linked by weak N-H⋯O hydrogen bonds, forming chains parallel to [100].

| S-EPMC3393910 | biostudies-literature

2,6-Diphenyl-3-(prop-2-en-1-yl)piperidin-4-one.

Project description:In the title compound, C20H21NO, the dihedral angle between the phenyl ring is 47.5 (1)° and the piperidine ring adopts a chair conformation. In the crystal, mol-ecules are linked by C-H⋯π inter-actions into dimers with the mol-ecules related by twofold symmetry.

| S-EPMC9462206 | biostudies-literature

1-(2-Azido-acet-yl)-3-methyl-2,6-diphenyl-piperidin-4-one.

Project description:In the title compound, C(20)H(20)N(4)O(2), the piperidine ring adopts a distorted boat conformation. The two phenyl rings form dihedral angles of 82.87?(1) and 84.40?(1)° with respect to the piperidine ring. The crystal packing is stabilized by inter-molecular C-H?O and C-H?N inter-actions.

| S-EPMC3009351 | biostudies-literature

1-(2-Bromo-acet-yl)-3-methyl-2,6-diphenyl-piperidin-4-one.

Project description:In the title compound, C(20)H(20)BrNO(2), the piperidone ring adopts a boat conformation. The phenyl rings are oriented at dihedral angles of 97.8?(2) and 96.0?(1)° with respect to the best plane through the piperidine ring. The dihedral angle between the two phenyl rings is 49.7?(1)°. In the crystal, bifurcated C-H?O hydrogen bonds form a R(2) (1)(7) ring motif, linking the mol-ecules into centrosymmetric dimers.

| S-EPMC2979607 | biostudies-literature

c-3,t-3-Dimethyl-r-2,c-6-diphenyl-piperidin-4-one.

Project description:In the title compound, C(19)H(21)NO, the piperidine ring adopts a chair conformation. The two phenyl rings attached to the piperidine ring at 2 and 6 positions occupy equatorial orientations and the dihedral angle between them is 57.53?(11)°. In the crystal, the mol-ecules are connected via weak inter-molecular C-H?? inter-actions, leading to a zigzag chains.

| S-EPMC2971408 | biostudies-literature

1-Chloro-acetyl-3-isopropyl-r-2,c-6-diphenyl-piperidin-4-one.

Project description:In the title compound, C(22)H(24)ClNO(2), the piperidine ring adopts a distorted boat conformation. The dihedral angle between the two phenyl rings is 83.2?(1)°. In the crystal, the mol-ecules are linked into chains running along the b axis by C-H?O hydrogen bonds. The Cl atom of the chloro-acetyl group is disordered over two positions with occupancies of 0.66?(2) and 0.34?(2).

| S-EPMC2979709 | biostudies-literature

Diphenyl (cyclo-pentyl-amido)-phospho-nate.

Project description:In the title mol-ecule, C(17)H(20)NO(3)P, the P atom is bonded in a distorted tetra-hedral environment. The dihedral angle between the two phenyl rings is 23.52?(10)°. The phosphoryl and N-H groups are anti with respect to one another. The -CH(2)-CH(2)-CH(2)-CH(2)- sequence of atoms in the cyclo-pentyl ring is disordered over two sets of sites with refined occupancies of 0.574?(10) and 0.426?(10). In the crystal, mol-ecules are linked via N-H?O=P hydrogen bonds to form extended chains along [010].

| S-EPMC3120324 | biostudies-literature

1-Acetyl-c-3,t-3-dimethyl-r-2,c-6-diphenyl-piperidin-4-one.

Project description:In the title compound, C(21)H(23)NO(2), the piperidine ring adopts a distorted boat conformation. The two phenyl rings form dihedral angles of 64.6?(1) and 87.8?(1)° with the best plane through the piperidine ring. The crystal packing is governed by inter-molecular C-H?O inter-actions.

| S-EPMC2977121 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data