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1-{2-[(2,4-Dichloro-benzyl-idene)amino]eth-yl}-3-methyl-imidazolium hexa-fluoro-phosphate.

ABSTRACT: In the title Schiff base compound, C(13)H(14)Cl(2)N(3) (+)·PF(6) (-), the dihedral angle between the aromatic ring and imidazole ring in the cation is 6.10?(2)°. Inter-molecular C-H?F hydrogen-bonding inter-actions and ?-? stacking inter-actions [centoid-centroid distance = 3.7203?(12)?Å] help stabilize the crystal packing.

SUBMITTER: Liu J

PROVIDER: S-EPMC2972013 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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1-{2-[(2,4-Dichloro-benzyl-idene)amino]eth-yl}-3-methyl-imidazolium hexa-fluoro-phosphate.

Liu Jie J Li Bin B Li Yi-Qun YQ Zheng Wen-Jie WJ

Acta crystallographica. Section E, Structure reports online 20091104 Pt 12

In the title Schiff base compound, C(13)H(14)Cl(2)N(3) (+)·PF(6) (-), the dihedral angle between the aromatic ring and imidazole ring in the cation is 6.10 (2)°. Inter-molecular C-H⋯F hydrogen-bonding inter-actions and π-π stacking inter-actions [centoid-centroid distance = 3.7203 (12) Å] help stabilize the crystal packing. ...[more]

PMID: 21578713

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