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Tris(methyl 3-oxobutanoato-?O,O')aluminium(III).

ABSTRACT: In the title compound, [Al(C(5)H(7)O(3))(3)], three acac-type ligands (methyl 3-oxobutanoate anions) chelate to the aluminium(III) cation in a slightly distorted AlO(6) octa-hedral coordination geometry. Electron delocalization occurs within the chelating rings.

SUBMITTER: Neelgund GM

PROVIDER: S-EPMC2972076 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Tris(methyl 3-oxobutanoato-κO,O')aluminium(III).

Neelgund Gururaj M GM Shivashankar S A SA Narasimhamurthy T T Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

In the title compound, [Al(C(5)H(7)O(3))(3)], three acac-type ligands (methyl 3-oxobutanoate anions) chelate to the aluminium(III) cation in a slightly distorted AlO(6) octa-hedral coordination geometry. Electron delocalization occurs within the chelating rings. ...[more]

PMID: 21578687

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