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Tris(ethyl-enediamine-?N,N')cobalt(III) aqua-tris-(oxalato-?O,O)indate(III).

ABSTRACT: In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(3)(H(2)O)], the Co(III) atom is coordinated by six N atoms from three ethyl-enediamine mol-ecules. The Co(III)-N bond lengths lie in the range 1.956?(4)-1.986?(4)?Å. In the anion, the In(III) atom is seven-coordinated by six O atoms from three oxalate ligands and by a water mol-ecule. The cations and anions are linked by extensive O-H?O and N-H?O hydrogen bonds, forming a supermolecular network.

SUBMITTER: Zhang Z

PROVIDER: S-EPMC3254329 | biostudies-literature | 2012 Jan

REPOSITORIES: biostudies-literature

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Tris(ethyl-enediamine-κN,N')cobalt(III) aqua-tris-(oxalato-κO,O)indate(III).

Zhang Zhe Z Wang Fuxiang F Liao Shuangquan S

Acta crystallographica. Section E, Structure reports online 20111217 Pt 1

In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(3)(H(2)O)], the Co(III) atom is coordinated by six N atoms from three ethyl-enediamine mol-ecules. The Co(III)-N bond lengths lie in the range 1.956 (4)-1.986 (4) Å. In the anion, the In(III) atom is seven-coordinated by six O atoms from three oxalate ligands and by a water mol-ecule. The cations and anions are linked by extensive O-H⋯O and N-H⋯O hydrogen bonds, forming a supermolecular network. ...[more]

PMID: 22259362

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