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2-Pyridone: monoclinic polymorph.

ABSTRACT: The asymmetric unit in the title compound, C(5)H(5)NO, comprises two independent but virtually identical mol-ecules of 2-pyridone, and represents a monoclinic polymorph of the previously reported ortho-rhom-bic (P2(1)2(1)2(1)) form [Penfold (1953 ?). Acta Cryst.6, 591-600; Ohms et al. (1984 ?). Z. Kristallogr.169, 185-200; Yang & Craven (1998 ?). Acta Cryst. B54, 912-920]. The independent mol-ecules are linked into supra-molecular dimers via eight-membered {?HNC(O)}(2) amide synthons in contrast to the helical supra-molecular chains, mediated by {?HNC(O)} links, found in the ortho-rhom-bic form.

SUBMITTER: Arman HD

PROVIDER: S-EPMC2972078 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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2-Pyridone: monoclinic polymorph.

Arman Hadi D HD Poplaukhin Pavel P Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

The asymmetric unit in the title compound, C(5)H(5)NO, comprises two independent but virtually identical mol-ecules of 2-pyridone, and represents a monoclinic polymorph of the previously reported ortho-rhom-bic (P2(1)2(1)2(1)) form [Penfold (1953 ▶). Acta Cryst.6, 591-600; Ohms et al. (1984 ▶). Z. Kristallogr.169, 185-200; Yang & Craven (1998 ▶). Acta Cryst. B54, 912-920]. The independent mol-ecules are linked into supra-molecular dimers via eight-membered {⋯HNC(O)}(2) amide synthons in contrast ...[more]

PMID: 21578899

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