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Methyl 2-(3-benzoyl-thio-ureido)acetate.

ABSTRACT: In the title compound, C(11)H(12)N(2)O(3)S, the methyl acetate and benzoyl groups adopt a cis-trans configuration with respect to the thiono S atom across the C-N bonds. An intra-molecular N-H?O hydrogen bond is observed. In the crystal packing, mol-ecules are linked by inter-molecular N-H?S and C-H?O hydrogen bonds to form a two-dimensional network lying parallel to (101).

SUBMITTER: Hassan IN

PROVIDER: S-EPMC2972120 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Methyl 2-(3-benzoyl-thio-ureido)acetate.

Hassan Ibrahim N IN Yamin Bohari M BM Kassim Mohammad B MB

Acta crystallographica. Section E, Structure reports online 20091114 Pt 12

In the title compound, C(11)H(12)N(2)O(3)S, the methyl acetate and benzoyl groups adopt a cis-trans configuration with respect to the thiono S atom across the C-N bonds. An intra-molecular N-H⋯O hydrogen bond is observed. In the crystal packing, mol-ecules are linked by inter-molecular N-H⋯S and C-H⋯O hydrogen bonds to form a two-dimensional network lying parallel to (101). ...[more]

PMID: 21578808

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Propyl 2-(3-benzoyl-thio-ureido)acetate.

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Project description:In the title compound, C(22)H(24)N(4)O(2)S(2), the two thio-urea segments of the side-arm groups are inclined at a dihedral angle of 73.09?(9)°. The central cyclo-hexane bridge adopts a chair conformation. The mol-ecule is stabilized by N-H?O intra-molecular hydrogen bonds forming S(6) rings, and N-H?O and N-H?S inter-molecular hydrogen bonds forming infinite chains developing parallel to the b axis.

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