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1,2-Bis(N'-benzoyl-thio-ureido)-4-chloro-benzene.

ABSTRACT: In the title compound, C(22)H(17)ClN(4)O(2)S(2), both benzoyl groups are trans to the thiono group across their C-N bonds. The two methyl-ene carbamothioyl formamide fragments of the benzoyl-thio-urea side arms make a dihedral angle of 87.00?(10)°. The mol-ecule is stabilized by intra-molecular N-H?O, N-H?S and C-H?·S hydrogen bonds. In the crystal, mol-ecules are linked by N-H?O and N-H?S inter-molecular hydrogen bonds into zigzag chains along the a axis.

SUBMITTER: Yamin BM

PROVIDER: S-EPMC3120362 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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1,2-Bis(N'-benzoyl-thio-ureido)-4-chloro-benzene.

Yamin Bohari M BM Osman Uwaisulqarni M UM

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

In the title compound, C(22)H(17)ClN(4)O(2)S(2), both benzoyl groups are trans to the thiono group across their C-N bonds. The two methyl-ene carbamothioyl formamide fragments of the benzoyl-thio-urea side arms make a dihedral angle of 87.00 (10)°. The mol-ecule is stabilized by intra-molecular N-H⋯O, N-H⋯S and C-H⋯·S hydrogen bonds. In the crystal, mol-ecules are linked by N-H⋯O and N-H⋯S inter-molecular hydrogen bonds into zigzag chains along the a axis. ...[more]

PMID: 21754693

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Methyl 3-(3-benzoyl-thio-ureido)propano-ate.

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