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Hexaaqua-cobalt(II) bis-(4-amino-3-methyl-benzene-sulfonate).

ABSTRACT: In the title mol-ecular salt, [Co(H(2)O)(6)](C(7)H(8)NO(3)S)(2), the Co(2+) cation lies on an inversion centre. In the crystal, the components are linked by N-H?O and O-H?O hydrogen bonds, thereby generating sheets parallel to (001).

SUBMITTER: Zhang W

PROVIDER: S-EPMC2972163 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Hexaaqua-cobalt(II) bis-(4-amino-3-methyl-benzene-sulfonate).

Zhang Wei W Chen Yuan-Tao YT

Acta crystallographica. Section E, Structure reports online 20091111 Pt 12

In the title mol-ecular salt, [Co(H(2)O)(6)](C(7)H(8)NO(3)S)(2), the Co(2+) cation lies on an inversion centre. In the crystal, the components are linked by N-H⋯O and O-H⋯O hydrogen bonds, thereby generating sheets parallel to (001). ...[more]

PMID: 21578587

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Hexaaqua-magnesium bis-(4-amino-3-methyl-benzene-sulfonate).

Project description:In the title mol-ecular salt, [Mg(H(2)O)(6)](C(7)H(8)NO(3)S)(2), the Mg(2+) cation lies on an inversion centre. In the crystal, the components are linked by N-H?O and O-H?O hydrogen bonds, thereby generating sheets parallel to (001).

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Hexaaqua-zinc(II) bis-[4-(2-hydroxy-benzyl-ideneamino)benzene-sulfonate].

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Project description:In the title compound, [Cd(H(2)O)(6)](C(13)H(10)NO(4)S)(2)·2H(2)O, the Cd atom (site symmetry ) adopts a regular octa-hedral coordination and the anion is stabilized by an intra-molecular O-H⋯N hydrogen bond. O-H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol-ecules lead to a three-dimensional network.

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Hexaaqua-zinc(II) bis-(4-hydroxy-benzene-sulfonate) dihydrate.

Project description:The asymmetric unit of the title hydrated mol-ecular salt, [Zn(H(2)O)(6)](C(6)H(5)O(4)S)(2)·2H(2)O, contains two half-cations, two anions and two uncoordinated water mol-ecules. Both cations are completed by crystallographic inversion symmetry, generating almost regular ZnO(6) octa-hedra. In the crystal, the cations, anions and uncoordinated water mol-ecules are linked by O-H?O hydrogen bonds, forming a three-dimensional network.

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Hexaaqua-nickel(II) bis-[4-(2-hydroxy-benzyl-ideneamino)benzene-sulfonate].

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Project description:The structure of the title complex, [Mg(H(2)O)(6)](C(10)H(15)O(4)S)(2), consists of regular octa-hedral [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. A three-dimensional supra-molecular architecture is formed via hydrogen-bond inter-actions [O-H?O = 2.723?(2)-2.833?(2)?Å] to give alternating layers of [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. The title compound is isomorphous with the zinc, copper, cadmium and nickel analogues.

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Hexaaqua-magnesium(II) bis-[4-(3-eth-oxy-2-hydroxy-benzyl-ideneamino)-3-methyl-benzene-sulfonate].

Project description:In the title compound, [Mg(H(2)O)(6)](C(16)H(16)NO(5)S)(2), the Mg(2+) ion (site symmetry 2) adopts an almost regular octa-hedral coordination geometry. The anion is stabilized by an intra-molecular O-H?N hydrogen bond, generating an S(6) ring, and the dihedral angle between the aromatic rings is 41.02?(7)°. In the crystal, the cations and anions are linked by O-H?O hydrogen bonds, generating sheets lying parallel to (100).

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