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Hexaaqua-magnesium bis-{4-[(5-bromo-2-hy-droxy-benzyl-idene)amino]-benzene-sulfonate} dihydrate.

ABSTRACT: In the title hydrated mol-ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry ) adopts a near regular MgO(6) octa-hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5?(2)° and an intra-molecular O-H?N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O-H?O and O-H?Br hydrogen bonds.

SUBMITTER: Tai XS 

PROVIDER: S-EPMC3051451 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Hexaaqua-magnesium bis-{4-[(5-bromo-2-hy-droxy-benzyl-idene)amino]-benzene-sulfonate} dihydrate.

Tai Xi-Shi XS  

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

In the title hydrated mol-ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry ) adopts a near regular MgO(6) octa-hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5 (2)° and an intra-molecular O-H⋯N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O-H⋯O and O-H⋯Br hydrogen bonds. ...[more]

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