Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Hexaaqua-magnesium bis-(4-amino-3-methyl-benzene-sulfonate).

ABSTRACT: In the title mol-ecular salt, [Mg(H(2)O)(6)](C(7)H(8)NO(3)S)(2), the Mg(2+) cation lies on an inversion centre. In the crystal, the components are linked by N-H?O and O-H?O hydrogen bonds, thereby generating sheets parallel to (001).

SUBMITTER: Zhang W

PROVIDER: S-EPMC2972177 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Hexaaqua-magnesium bis-(4-amino-3-methyl-benzene-sulfonate).

Zhang Wei W Chen Yuan-Tao YT

Acta crystallographica. Section E, Structure reports online 20091111 Pt 12

In the title mol-ecular salt, [Mg(H(2)O)(6)](C(7)H(8)NO(3)S)(2), the Mg(2+) cation lies on an inversion centre. In the crystal, the components are linked by N-H⋯O and O-H⋯O hydrogen bonds, thereby generating sheets parallel to (001). ...[more]

PMID: 21578588

Similar Datasets

Hexaaqua-cobalt(II) bis-(4-amino-3-methyl-benzene-sulfonate).

Project description:In the title mol-ecular salt, [Co(H(2)O)(6)](C(7)H(8)NO(3)S)(2), the Co(2+) cation lies on an inversion centre. In the crystal, the components are linked by N-H?O and O-H?O hydrogen bonds, thereby generating sheets parallel to (001).

| S-EPMC2972163 | biostudies-literature

Hexaaqua-magnesium bis-{4-[(5-bromo-2-hy-droxy-benzyl-idene)amino]-benzene-sulfonate} dihydrate.

Project description:In the title hydrated mol-ecular salt, [Mg(H(2)O)(6)](C(13)H(9)BrNO(4)S)(2)·2H(2)O, the Mg(2+) ion (site symmetry ) adopts a near regular MgO(6) octa-hedral coordination geometry. In the anion, the dihedral angle between the aromatic rings is 2.5?(2)° and an intra-molecular O-H?N hydrogen bond generates an S(6) ring. In the crystal, the components are linked by O-H?O and O-H?Br hydrogen bonds.

| S-EPMC3051451 | biostudies-literature

Hexaaqua-magnesium bis-(3-carb-oxy-4-hy-droxy-benzene-sulfonate) dihydrate.

Project description:In the crystal structure of the title compound, [Mg(H(2)O)(6)](C(7)H(5)O(6)S)(2)·2H(2)O, the octa-hedral complex cation lies on an inversion centre and is hydrogen bonded through the coordinated water molecules to the substituted benzene-sulfonate monoanions and the water mol-ecules of solvation. These inter-actions together with a carb-oxy-lic acid O-H?O(sulfonate) association give a three-dimensional structure.

| S-EPMC3200685 | biostudies-literature

Hexaaqua-magnesium(II) bis-(d-camphor-10-sulfonate).

Project description:The structure of the title complex, [Mg(H(2)O)(6)](C(10)H(15)O(4)S)(2), consists of regular octa-hedral [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. A three-dimensional supra-molecular architecture is formed via hydrogen-bond inter-actions [O-H?O = 2.723?(2)-2.833?(2)?Å] to give alternating layers of [Mg(H(2)O)(6)](2+) cations and d-camphor-10-sulfonate anions. The title compound is isomorphous with the zinc, copper, cadmium and nickel analogues.

| S-EPMC2961654 | biostudies-literature

Hexaaqua-magnesium(II) bis-[4-(3-eth-oxy-2-hydroxy-benzyl-ideneamino)-3-methyl-benzene-sulfonate].

Project description:In the title compound, [Mg(H(2)O)(6)](C(16)H(16)NO(5)S)(2), the Mg(2+) ion (site symmetry 2) adopts an almost regular octa-hedral coordination geometry. The anion is stabilized by an intra-molecular O-H?N hydrogen bond, generating an S(6) ring, and the dihedral angle between the aromatic rings is 41.02?(7)°. In the crystal, the cations and anions are linked by O-H?O hydrogen bonds, generating sheets lying parallel to (100).

| S-EPMC2983805 | biostudies-other

Hexaaqua-zinc(II) bis-(4-hydroxy-benzene-sulfonate) dihydrate.

Project description:In the crystal structure of the title compound, [Zn(H(2)O)(6)](C(6)H(5)O(4)S)(2)·2H(2)O, the Zn(II) atom lies on a center of inversion. The complex cation inter-acts with the anion and uncoord-inated water mol-ecules by O-H?O hydrogen bonds, generating a three-dimensional network. The anion is disordered over two equal positions along the hydr-oxy-sulfonate C-C axis.

| S-EPMC2971186 | biostudies-literature

Hexaaqua-zinc(II) bis-[4-(2-hydroxy-benzyl-ideneamino)benzene-sulfonate].

Project description:In the title compound, [Zn(H(2)O)(6)](C(13)H(10)NO(4)S)(2), a distorted ZnO(6) octa-hedron results from the coordination by the six water mol-ecules. Only three of the water molecules are crystallographically unique, as the Zn atom lies on an inversion center. The Zn-O bond lengths are in the range 2.054 (4)-2.073 (4) Å. A network of hydrogen bonds helps to establish the crystal packing.

| S-EPMC2960324 | biostudies-literature

6-Amino-9H-purine-1,7-diium bis-(4-methyl-benzene-sulfonate) monohydrate.

Project description:The asymmetric unit of the title compound, C(5)H(7)N(5) (2+)·2C(7)H(7)O(3)S(-)·H(2)O, consists of one diprotonated adeninium cation, two p-toluene-sulfonic acid anions and one water mol-ecule. In the crystal, the cations and anions are connected through N-H?O hydrogen bonds forming R(2) (2)(8) and R(2) (2)(9) graph-set motifs. The solvent water mol-ecule links cations and anions through O-H?O and N-H?O hydrogen bonds, generating a two-dimensional layer parallel to (10).

| S-EPMC2979717 | biostudies-literature

Hexaaqua-cadmium(II) bis-[4-(2-hydroxy-benzyl-ideneamino)benzene-sulfonate] dihydrate.

Project description:In the title compound, [Cd(H(2)O)(6)](C(13)H(10)NO(4)S)(2)·2H(2)O, the Cd atom (site symmetry ) adopts a regular octa-hedral coordination and the anion is stabilized by an intra-molecular O-H?N hydrogen bond. O-H?O hydrogen bonds involving the coordinated and uncoordinated water mol-ecules lead to a three-dimensional network.

| S-EPMC2961211 | biostudies-literature

Hexaaqua-magnesium(II) bis-[4-(3-pyrid-yl)pyrimidine-2-sulfonate] tetra-hydrate.

Project description:The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(6)N(3)O(3)S)(2)·4H(2)O, contains half of a centrosymmetric cation, one 4-(3-pyrid-yl)pyrimidin-2-sulfonate anion and two solvent water mol-ecules. Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds link the cations, anions and water mol-ecules into a three-dimensional supra-molecular structure. The crystal packing also exhibits inter-molecular π-π inter-actions between the aromatic rings of the anions with a centroid-centroid distance of 3.604 (2) Å.

| S-EPMC2970970 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data